A "freeroll" is a tournament with some prize, but no entry fee.
"freerolling" is when you have part of the pot locked up, and and have a chance to win the whole thing.
Ex: you have

your opponent has
The flop is

you have half the pot locked up, but are "freerolling" to hit your flush and scoop the whole pot.
Similar to hi/lo games where you have the low side locked up vs a high hand, and you have outs to beat his high.